Optimization Algorithm-Assisted Nanostructure Engineering for Performance Enhancement of Thin-Film Solar Cells

RESUMO

A computation-based study is presented that utilizes the finite-difference time-domain (FDTD) method to perform optical simulations. These simulations were used to observe the effects of core-shell nanostructures with triangular cross-sections embedded inside the light absorbing layer of thin-film solar cells (TFSCs), for improving the optoelectronic performance. Despite extensive research, the relationship between the geometric parameters of light trapping nanostructures and TFSC performance is not yet fully elucidated. To assist in finding the optimal set of parameters, optimization algorithms are used to find a set of parameters that provide maximal short-circuit current density ($J_{SC}$). Three separate algorithms were applied, and the results were scrutinized in-depth with a sensitivity analysis, observing the effects of small changes in the optimal parameters. The optimal parameters of the nanostructure produced $J_{SC}$ values ranging from 28.90 to 35.39 mA/cm$^2$ compared to 13.69 mA/cm$^2$ for a reference TFSC with no nanostructure present. From the results of this study, it can be inferred that optimized periodic grating structures can provide substantial improvement in performance of TFSCs.