Percolation threshold in cluster-assembled nanogranular palladium films and related strategies for hydrogen detection

RESUMO

Electrical transport in cluster-assembled nanogranular palladium films was investigated in-situ during growth by Supersonic Cluster Beam Deposition. The percolation onset is observed at a thickness of 1.5 nm, while the percolation completion at 2.5 nm. Films at the percolation thickness (2 nm) and beyond the percolation end (5 nm) were subsequently exposed ex-situ to 0.25% hydrogen in air to investigate how hydrogen-induced structural changes in Pd clusters modulate electrical transport and can be exploited as mechanism for selective hydrogen detection. Implantation of palladium clusters in soft polymer styrene-ethylene-butylene-styrene was also explored to promote clusters separation and enhance quantum tunnelling phenomena within electrical transport. The observed electrical transport pattern features stable baselines in air, suggesting material stability, fast response time (T50% < 10 s), and the coexistence of reversible and irreversible components in conduction changes induced by hydrogen exposure. The irreversible component is tentatively attributed to hydrogen-promoted partial coalescence of Pd clusters. The behaviour of the polymer implanted samples suggests an alternative gas detection mechanism where hydrogen-induced polymer swelling dominates over palladium structural modifications. These results disclose novel possible transducing routes for miniaturized hydrogen detection and multimodal sensing.