Nuclear slowing-down factors in alkali-metal vapors

RESUMO

Nuclear slowing-down factors account for the sharing of angular momentum between the electron and the nucleus in the effective Bloch description of alkali-metal spin dynamics in the spin-exchange-relaxation-free (SERF) regime. For collinear optical pumping and magnetic field, we find that longitudinal and transverse spin dynamics are characterized by different polarization-dependent slowing-down factors. Transverse dynamics are governed by the conventional factor $q(p)$, with $p$ the electron spin polarization, whereas longitudinal relaxation is governed by $q(p)+p\,dq(p)/dp$. The two factors coincide at zero polarization but differ substantially at high polarization, where the single-factor description overestimates the underlying pumping and relaxation rates inferred from longitudinal transients by factors approaching two to four, depending on the nuclear spin. We further derive closed-form expressions, valid at arbitrary polarization, for the residual spin-exchange relaxation of the transverse spin components at finite magnetic field along the pumping axis. This contribution is quadratic in the magnetic field and can become comparable to the zero-field linewidth at fields well within the SERF regime. The results are obtained by perturbation theory on the density-matrix dynamics linearized around the stationary state and are verified by numerical solutions of the microscopic density-matrix equation. These findings refine the effective Bloch description of alkali-metal spin dynamics and are directly relevant to atomic magnetometers and alkali-metal--noble-gas comagnetometers, including those used in precision searches for physics beyond the Standard Model.