Directional memory of early spectral selection during spinodal decomposition in finite systems

RESUMO

Cahn-Hilliard phase separation turns small composition fluctuations into coarsening domains. In Fourier space, the pattern forms a ring whose angular intensity favors an axis. We ask whether the axis favored early in an evolution remains related to the axis favored later in the same evolution. We analyze two-dimensional simulations with isotropic initial fluctuations and no imposed direction. We introduce $Q_2$, a normalized angular average over the Fourier spectrum, as a measure of the strength and direction of spectral anisotropy. Linear growth amplifies different wave numbers at different rates, selecting an early axis from the angular imbalances in the initial spectrum. This axis remains correlated with the late axis during coarsening. At a fixed time, shallow quenches show stronger early-late alignment. This advantage disappears when the quenches are compared at similar stages of domain growth. Adding the early $Q_2$ to a prediction based on quench depth, mean composition, and box size reduces the mean absolute error for late $Q_2$ by $3.53\%$. This reduction disappears when only the magnitude of the early $Q_2$ is retained, or when its direction is replaced by the direction from another evolution. The early Fourier intensity therefore carries information about the later state of the same evolving field.