Activated carbon-assisted anionic dye decomposition using a dual-liquid post-double dielectric barrier discharge plasma reactor

RESUMO

Non-thermal Plasma (NTP) technology, including the Dielectric Barrier Discharge (DBD) reactor, has emerged as an effective advanced oxidation process (AOP) for treating persistent organic pollutants in industrial wastewater. Based on this objective, a dual-liquid dielectric-barrier-discharge plasma reactor was built and used to degrade a ternary anionic dye mixture comprising Reactive Red 120, Congo Red, and Methyl Orange in its post-discharge configuration. The adjustable length of the outer liquid electrode (grounded) provides flexibility in controlling the discharge length and cooling, thereby achieving higher degradation efficiency and greater reactor stability. The conducting-liquid high-voltage electrode (a dielectric tube filled with a conductive solution) helps mitigate metal corrosion and oxidation caused by reactive species in the discharge zone. A detailed study of the degradation of ternary anionic dye mixtures (simulated dye wastewater samples) in the presence of activated carbon (AC) was performed to explore the potential applications of post-discharge treatment. The activated carbon (granules) enhances the degradation rate of ternary anionic dye mixtures in basic solutions rather than in acidic or neutral solutions. A comparative study of the degradation reaction kinetics of the ternary anionic dye mixtures in acidic and basic solutions was conducted after analyzing UV-Vis absorption spectra. The role of other parameters, such as solution pH, the mass and size of AC particles, dye concentrations, and AC reuse, was investigated in relation to degradation efficiency. The degradation mechanism was elucidated by the formation of strong oxidizer (hydroxyl radicals) on the surface of activated carbon during post-discharge treatment. However, in acidic or neutral anionic dye solutions, the degradation mechanism was dominated by ozone.